Zinc_Aerosol_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : Zinc Creationdate : 11.05.20 Version : 5.1
Ref.Nr.: BDS000467_3_20200511 (EN) Replaces: BDS000467_20200401
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
Zinc
Aerosol
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Paints
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries Europe BV
Touwslagerstraat 1
9240 Zele
Belgium
Tel.: +32(0)52/45.60.11
Fax.: +32(0)52/45.00.34
E-mail : hse@crcind.com
 
SubsidiariesTelFax
CRC Industries Finland OySmedsgatan 3-5 LT4, PL62, 08101 LOJO+358/(19)32.921
CRC Industries France6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex01.34.11.20.0001.34.11.09.96
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303 0(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA0034/921.427.5460034/921.436.270
CRC Industries SwedenLaxfiskevägen 16, 433 38 Partille0046/31 706 84 800046/31 27 39 91
 
1.4. Emergency telephone number
 
 
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Aerosols, category 1
 Extremely flammable aerosol.
 Pressurised container: May burst if heated.
Classification is based on test data.
Health: Eye irritation, category 2
 Causes serious eye irritation.
 Specific target organ toxicity - single exposure, category 3
 May cause drowsiness or dizziness.
 Specific Target Organ Toxicity - Repeated Exposure Category 2
 May cause damage to organs through prolonged or repeated exposure .
Classification based on calculation method.
Environment: Hazardous to the aquatic environment, acute category 1
 Very toxic to aquatic life.
 Hazardous to the aquatic environment, chronic category 1
 Very toxic to aquatic life with long lasting effects.
Classification based on calculation method.
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Product identifier: Contains:
 hydrocarbons
Hazard pictogram(s):
Signal word: Danger
Hazard statement(s): H222 : Extremely flammable aerosol.
 H229 : Pressurised container: May burst if heated.
 H319 : Causes serious eye irritation.
 H336 : May cause drowsiness or dizziness.
 H373 : May cause damage to organs through prolonged or repeated exposure .
 H410 : Very toxic to aquatic life with long lasting effects.
Precautionary statement(s): P102 : Keep out of reach of children.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
 P211 : Do not spray on an open flame or other ignition source.
 P251 : Do not pierce or burn, even after use.
 P261-1 : Avoid breathing vapours/spray.
 P280 : Wear protective gloves/protective clothing/eye protection/face protection.
P337/313 : If eye irritation persists: Get medical advice/attention.
 P333/313 : If skin irritation or rash occurs: Get medical advice/attention.
P410/412 : Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
P501-2 : Dispose of contents/container to an authorised waste collection point.
Supplemental Hazard information: Contains:
 2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime
 May produce an allergic reaction.
 
Dir. 2004/42/EC on the limitation of emmissions of volatile organic compounds (VOC) of organic solvents in certain paints and varnishes and vehicle refinishing productsCat.II B(e) VOC max 840 g/L < 640 g/L
 
2.3. Other hazards
 
No information available
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
dimethyl ether01-2119472128-37115-10-6204-065-825-50Flam. Gas 1, Press. GasH220,H280A
zinc powder - zinc dust (stabilized)01-2119467174-377440-66-6231-175-310-25Aquatic Acute 1, Aquatic Chronic 1H400,H410
Hydrocarbons, C9-12, n-alkanes, isoalkanes, cyclic01-2119458049-3364742-82-1(919-446-0)<10Flam. Liq. 3, Asp. Tox. 1, STOT SE 3, STOT RE 1, Aquatic Chronic 2H226,H304,H336,H372,H411B,Q
butanone; ethyl methyl ketone01-2119457290-4378-93-3201-159-0<10Flam. Liq. 2, Eye Irrit. 2, STOT SE 3H225,H319,H336A
Hydrocarbons, C6-C7, n-alkanes,isoalkanes,cyclics,< 5% n-hexane01-2119475514-35-(921-024-6)<8Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2H225,H315,H336,H304,H411B,Q
zinc oxide01-2119463881-321314-13-2215-222-5<5Aquatic Acute 1, Aquatic Chronic 1H400,H410B
2-(3-heptyl)-N-butyl-1,3-oxazolane165101-57-5425-660-0<1Aquatic Chronic 2H411
butan-1-ol; n-butanol01-2119484630-3871-36-3200-751-6<1Flam. Liq. 3, Acute Tox. 4, Skin Irrit. 2, Eye Dam. 1, STOT SE 3, STOT SE 3H226,H302,H315,H318,H335,H336B
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime01-2119539477-2896-29-7202-496-6<1Carc. 2, Acute Tox. 4, Eye Dam. 1, Skin Sens. 1H351,H312,H318,H317B
Fatty acids, C18-unsatd., dimers, compds. with coco alkylamines-68647-95-0614-682-8<0.1Skin Irrit. 2, Skin Sens. 1, STOT RE 2, Aquatic Acute 1, Aquatic Chronic 1H315,H317,H373,H400,H410
Explanation notes
A : substance with Community workplace exposure limit
B : substance with national established workplace exposure limit
Q : The CAS-no is only an indicative identifier to be used outside the EU for global inventory entries.
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 If eye irritation persists: Get medical advice/attention.
Contact with skin : Take off contaminated clothing and wash before reuse.
 IF ON SKIN: Wash with plenty of water.
 If skin irritation occurs: Get medical advice/attention.
Inhalation : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
 Call a POISON CENTER or doctor/physician if you feel unwell.
Ingestion : If swallowed accidentally, do not induce vomiting and seek medical advice.
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : May cause gastrointestinal disturbances
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : May cause irritation.
 Symptoms : redness and pain
Eye contact : Irritating to eyes
 Symptoms : redness and pain
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
Aerosols may explode if heated above 50°C
Forms hazardous decomposition products
CO,CO2
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Ensure adequate ventilation
Wear suitable protective clothing and gloves.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
Place in appropriate container
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Keep away from heat and sources of ignition
Take precautionary measures against static discharges
Equipment should be earthed
Use explosion-proof electrical/ventilating/lighting/.../equipment.
Use only non-sparking tools.
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
Eyewash bottles should be available
 
7.2. Conditions for safe storage, including any incompatibilities
 
Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Paints
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
dimethyl ether115-10-6TWA1000 ppm
butanone; ethyl methyl ketone78-93-3TWA200 ppm
STEL300 ppm
National established exposure limits, United Kingdom
dimethyl ether115-10-6TWA400 ppm
STEL500 ppm
butan-1-ol; n-butanol71-36-3STEL50 ppm
butanone; ethyl methyl ketone78-93-3TWA200 ppm
STEL300 ppm
National established exposure limits, Ireland
dimethyl ether115-10-6TWA1000 ppm
STEL-
butan-1-ol; n-butanol71-36-3TWA20 ppm
butanone; ethyl methyl ketone78-93-3TWA200 ppm
STEL300 ppm
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7TWA3 ppm
STEL10 ppm
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
 Keep away from heat and sources of ignition
 Take precautionary measures against static discharges
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
 Ensure adequate ventilation
 Wear suitable protective gloves
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with organic gas/vapor cartridge (type AX)
hands and skin : When handling the product wear chemical-resistant gloves (standard EN 374).
 The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through.
Recommended gloves: Nitrile
eyes : Wear safety eyewear according to EN 166.
Environmental protection: Avoid release to the environment.
 Collect spillage.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
(for aerosols data for the product without propellant)
Appearance : physical state : DME propelled liquid.
colour : Grey.
odour : Characteristic odor.
pH : Not applicable.
Boiling point/range : Not available.
Flash point : < 0 °C
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 1.45 g/cm3 (@ 20°C).
Solubility in water : Insoluble in water
Auto-ignition : > 200 °C
Viscosity : Not available.
 
9.2. Other information
 
VOC = volatile organic compounds 640 g/l
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Avoid overheating
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
acute toxicity: based on available data the classification criteria are not met
skin corrosion/irritation: based on available data the classification criteria are not met
serious eye damage/irritation: Causes serious eye irritation.
respiratory or skin sensitisation: based on available data the classification criteria are not met
germ cell mutagenicity: based on available data the classification criteria are not met
carcinogenicity: based on available data the classification criteria are not met
toxicity for reproduction: based on available data the classification criteria are not met
STOT-single exposure: May cause drowsiness or dizziness.
STOT repeated exposure: May cause damage to organs through prolonged or repeated exposure .
aspiration hazard: based on available data the classification criteria are not met
 
Information on likely routes of exposure:
 
Inhalation : Inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : May cause gastrointestinal disturbances
Skin contact : May cause irritation.
Eye contact : Irritating to eyes
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
dimethyl ether115-10-6LC50 inhal.rat309 mg/l
zinc oxide1314-13-2LD50 oral rat7950 mg/kg
LC50 inhal.rat> 5.7 mg/l
butan-1-ol; n-butanol71-36-3LD50 oral rat2292 mg/kg
LC50 inhal.rat> 17.76 mg/l
LD50 derm.rabit3430 mg/kg
butanone; ethyl methyl ketone78-93-3LD50 oral rat> 2000 mg/kg
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7LD50 oral rat2326 mg/kg
LD50 derm.rabit1000 mg/kg
Hydrocarbons, C9-12, n-alkanes, isoalkanes, cyclic64742-82-1LD50 oral rat> 5000 mg/kg
LC50 inhal.rat> 10 mg/l
LD50 derm.rabit> 4 mg/kg
Hydrocarbons, C6-C7, n-alkanes,isoalkanes,cyclics,< 5% n-hexane-LD50 oral rat> 5000 mg/kg
LC50 inhal.rat> 25000 mg/m3
LD50 derm.rat> 2000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Hazardous to the aquatic environment, acute category 1
Very toxic to aquatic life.
Hazardous to the aquatic environment, chronic category 1
Very toxic to aquatic life with long lasting effects.
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
dimethyl ether115-10-6IC50 algae154.9 mg/l
LC50 fish4.1 mg/l
EC50 daphnia4.4 mg/l
zinc oxide1314-13-2IC50 algae0.136 mg/l
LC50 fish0.169 mg/l
EC50 daphnia1.7 mg/l
butan-1-ol; n-butanol71-36-3LC50 fish1376 mg/l
EC50 daphnia1328 mg/l
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7IC50 algae11.8 mg/l
LC50 fish> 100 mg/l
EC50 daphnia201 mg/l
Hydrocarbons, C9-12, n-alkanes, isoalkanes, cyclic64742-82-1IC50 algae4.6-10 mg/l
LC50 fish10-30 mg/l
EC50 daphnia10-22 mg/l
Hydrocarbons, C6-C7, n-alkanes,isoalkanes,cyclics,< 5% n-hexane-LC50 fish> 10 mg/l
EC50 daphnia3 mg/l
 
12.2. Persistence and degradability
 
No experimental data available
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Insoluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
No experimental data available
GWP (global warming potential): 1
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
National regulations : Disposal should be in accordance with local, state or national legislation
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : 1950
 
14.2. UN proper shipping name
 
Proper shipping name: AEROSOLS
 
14.3. Transport hazard class(es)
 
Class: 2.1
ADR/RID - Classification code: 5F
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: (D)
IMDG - Ems: F-D, S-U
IATA/ICAO - PAX: 203
IATA/ICAO - CAO 203
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Regulation (EC) No 1907/2006 (REACH)
Regulation (EC) No 1272/2008 (CLP)
Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: H220 : Extremely flammable gas.
 H225 : Highly flammable liquid and vapour.
 H226 : Flammable liquid and vapour.
 H280 : Contains gas under pressure; may explode if heated.
 H302 : Harmful if swallowed.
 H304 : May be fatal if swallowed and enters airways.
 H312 : Harmful in contact with skin.
 H315 : Causes skin irritation.
 H317 : May cause an allergic skin reaction.
 H318 : Causes serious eye damage.
 H319 : Causes serious eye irritation.
 H335 : May cause respiratory irritation.
 H336 : May cause drowsiness or dizziness.
 H351 : Suspected of causing cancer .
 H372 : Causes damage to organs through prolonged or repeated exposure.
 H373 : May cause damage to organs through prolonged or repeated exposure .
 H400 : Very toxic to aquatic life.
 H410 : Very toxic to aquatic life with long lasting effects.
 H411 : Toxic to aquatic life with long lasting effects.
acronyms and synonyms: TWA = time weight average
 STEL = short time exposure limit
 VOC = volatile organic compounds
 PBT = persistant bioaccumulative toxic
 vPvB = very persitant very bioaccumulative
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.