Urethane Isolation_Bulk_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : Urethane Isolation Creationdate : 27.02.19 Version : 4.0
Ref.Nr.: BDS001076_3_20190227 (EN) Replaces: BDS001076_20170629
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
Urethane Isolation
Bulk
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Anti Corrosion Products
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries Europe bvba
Touwslagerstraat 1
9240 Zele
Belgium
Tel.: +32(0)52/45.60.11
Fax.: +32(0)52/45.00.34
E-mail : hse@crcind.com
 
SubsidiariesTelFax
CRC Industries Finland OySmedsgatan 3-5 LT4, PL62, 08101 LOJO+358/(19)32.921
CRC Industries France6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex01.34.11.20.0001.34.11.09.96
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303 0(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA0034/921.427.5460034/921.436.270
CRC Industries SwedenLaxfiskevägen 16, 433 38 Partille0046/31 706 84 800046/31 27 39 91
 
1.4. Emergency telephone number
 
 
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Flammable liquid, category 3
 Flammable liquid and vapour.
Classification is based on test data.
Health: Acute toxicity, category 4
 Harmful if inhaled.
 Specific Target Organ Toxicity - Repeated Exposure Category 2
 Causes damage to organs through prolonged or repeated exposure.
Classification based on calculation method.
Environment: Not classified
Classification based on calculation method.
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Product identifier: Contains:
 Stoddard solvent; Low boiling point naphtha - unspecified
Hazard pictogram(s):  
Signal word: Danger
Hazard statement(s): H226 : Flammable liquid and vapour.
 H332 : Harmful if inhaled.
 H372 : Causes damage to organs through prolonged or repeated exposure.
Precautionary statement(s): P102 : Keep out of reach of children.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
 P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
P312 : Call a POISON CENTER or doctor/physician if you feel unwell.
P501-2 : Dispose of contents/container to an authorised waste collection point.
Supplemental Hazard information: Contains:
 2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime
 May produce an allergic reaction.
 
2.3. Other hazards
 
No information available
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
Stoddard solvent; Low boiling point naphtha - unspecified01-2120261965-458052-41-3232-489-325-50Asp. Tox. 1, STOT RE 1H304,H372B,P
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime01-2119539477-2896-29-7202-496-6<1Carc. 2, Acute Tox. 4, Eye Dam. 1, Skin Sens. 1H351,H312,H318,H317B
1,2,4-trimethylbenzene01-2119472135-4295-63-6202-436-9<2.5Flam. Liq. 3, Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2, STOT SE 3, Aquatic Chronic 2H226,H332,H315,H319,H335,H411A
Explanation notes
A : substance with Community workplace exposure limit
B : substance with national established workplace exposure limit
P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753-7)
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
 If eye irritation persists: Get medical advice/attention.
Contact with skin : Remove contaminated clothing immediately and drench affected skin with plenty of water. Then wash with soap and water
 Seek medical advice
Inhalation : IF INHALED:
 Apply artificial respiration only if patient is not breathing
 Call a POISON CENTER or doctor/physician if you feel unwell.
Ingestion : If swallowed accidentally, do not induce vomiting and seek medical advice.
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : Harmful by inhalation.
 Symptoms : sore throat, cough, shortness of breath, headache
Ingestion : May induce chemical pneumonia.
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : May cause sensitization by skin contact.
 Symptoms : redness and pain
Eye contact : Symptoms : redness and pain
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
Forms hazardous decomposition products
CO,CO2
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Use only outdoors or in a well-ventilated area.
Wear suitable protective clothing and gloves.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
Place in appropriate container
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Use explosion-proof electrical/ventilating/lighting/.../equipment.
Use only non-sparking tools.
Do not breathe aerosols or vapours.
Use only outdoors or in a well-ventilated area.
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
 
7.2. Conditions for safe storage, including any incompatibilities
 
Keep in a cool, dry, well ventilated place
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Anti Corrosion Products
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
1,2,4-trimethylbenzene95-63-6TWA20 ppm
National established exposure limits, Ireland
Stoddard solvent; Low boiling point naphtha - unspecified8052-41-3TWA100 ppm
STEL125 ppm
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7TWA3 ppm
STEL10 ppm
 
8.2. Exposure controls
 
Control procedures : Use only outdoors or in a well-ventilated area.
 Keep away from heat and sources of ignition
 Take precautionary measures against static discharges
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
 Do not breathe aerosols or vapours.
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with organic gas/vapor cartridge (type A)
hands and skin : When handling the product wear chemical-resistant gloves (standard EN 374).
Recommended gloves: Nitrile
eyes : Wear safety eyewear according to EN 166.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
Appearance : physical state : Liquid.
colour : Red.
odour : Solvent.
pH : Not applicable.
Boiling point/range : Not available.
Flash point : 36 °C (Closed Cup)
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 0.92 g/cm3 (@ 20°C).
Solubility in water : Insoluble in water
Auto-ignition : > 200 °C
Viscosity : 111 mPa.s (@ 20°C).
 
9.2. Other information
 
VOC = volatile organic compounds 740 g/l
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Avoid overheating
 
10.5. Incompatible materials
 
alkali metals
alkaline earth metals
metal salts
 
10.6. Hazardous decomposition products
 
CO,CO2
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
acute toxicity: Harmful if inhaled.
skin corrosion/irritation: based on available data the classification criteria are not met
serious eye damage/irritation: based on available data the classification criteria are not met
respiratory or skin sensitisation: based on available data the classification criteria are not met
germ cell mutagenicity: based on available data the classification criteria are not met
carcinogenicity: based on available data the classification criteria are not met
toxicity for reproduction: based on available data the classification criteria are not met
STOT-single exposure: based on available data the classification criteria are not met
STOT repeated exposure: Causes damage to organs through prolonged or repeated exposure.
aspiration hazard: based on available data the classification criteria are not met
 
Information on likely routes of exposure:
 
Inhalation : Harmful by inhalation.
 Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : May cause gastrointestinal disturbances
Skin contact : May cause sensitization by skin contact.
Eye contact : May cause irritation.
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7LD50 oral rat2326 mg/kg
LD50 derm.rabit1000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Not classified
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7IC50 algae11.8 mg/l
LC50 fish> 100 mg/l
EC50 daphnia201 mg/l
 
12.2. Persistence and degradability
 
No experimental data available
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Insoluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
No experimental data available
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : 1263
 
14.2. UN proper shipping name
 
Proper shipping name: PAINT
 
14.3. Transport hazard class(es)
 
Class: 3
ADR/RID - Classification code: F1
 
14.4. Packing group
 
Packing group: III
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: (D/E)
IMDG - Ems: F-E, S-D
IATA/ICAO - PAX: 355
IATA/ICAO - CAO 366
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Regulation (EC) No 1907/2006 (REACH)
Regulation (EC) No 1272/2008 (CLP)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: H226 : Flammable liquid and vapour.
 H304 : May be fatal if swallowed and enters airways.
 H312 : Harmful in contact with skin.
 H315 : Causes skin irritation.
 H317 : May cause an allergic skin reaction.
 H318 : Causes serious eye damage.
 H319 : Causes serious eye irritation.
 H332 : Harmful if inhaled.
 H335 : May cause respiratory irritation.
 H351 : Suspected of causing cancer .
 H372 : Causes damage to organs through prolonged or repeated exposure.
 H411 : Toxic to aquatic life with long lasting effects.
REVISIONS IN CHAPTRE : Labelling according to Regulation (EC) No 1272/2008
acronyms and synonyms: TWA = time weight average
 STEL = short time exposure limit
 VOC = volatile organic compounds
 PBT = persistant bioaccumulative toxic
 vPvB = very persitant very bioaccumulative
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.