Anti Spatter_Bulk_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : Anti Spatter Creationdate : 29.06.17 Version : 3.0
Ref.Nr.: BDS001081_3_20170629 (EN) Replaces: BDS001081_20150602
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
Anti Spatter
Bulk
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Welding Products
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries Europe bvba
Touwslagerstraat 1
9240 Zele
Belgium
Tel.: +32(0)52/45.60.11
Fax.: +32(0)52/45.00.34
E-mail : hse@crcind.com
 
SubsidiariesTelFax
CRC Industries Finland OyLaurinkatu 57 A 23 B, 08100 Lohja+358/(19)32.921
CRC Industries France6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex01.34.11.20.0001.34.11.09.96
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303 0(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA0034/921.427.5460034/921.436.270
CRC Industries SwedenLaxfiskevägen 16, 433 38 Partille0046/31 706 84 800046/31 27 39 91
 
1.4. Emergency telephone number
 
 
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Not classified
Classification is based on test data.
Health: Carcinogenicity, category 2
 Suspected of causing cancer .
 Skin irritation, category 2
 Causes skin irritation.
 Eye irritation, category 2
 Causes serious eye irritation.
 Specific target organ toxicity - single exposure, category 3
 May cause drowsiness or dizziness.
Classification based on calculation method.
Environment: Not classified
Classification based on calculation method.
Other hazards : Not classified
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Product identifier: Contains:
 dichloromethane; methylene chloride
Hazard pictogram(s):    
Signal word: Warning
Hazard statement(s): H351 : Suspected of causing cancer .
 H315 : Causes skin irritation.
 H319 : Causes serious eye irritation.
 H336 : May cause drowsiness or dizziness.
Precautionary statement(s): P102 : Keep out of reach of children.
P201 : Obtain special instructions before use.
 P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
 P271 : Use only outdoors or in a well-ventilated area.
 P280 : Wear protective gloves/protective clothing/eye protection/face protection.
P305/351/338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 P308/313 : IF exposed or concerned: Get medical advice/attention.
P405 : Store locked up.
P501-2 : Dispose of contents/container to an authorised waste collection point.
 
2.3. Other hazards
 
The product does not contain any PBT or vPvB substances.
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
dichloromethane; methylene chloride01-2119480404-4175-09-2200-838-975-100Carc. 2, Skin Irrit. 2, Eye Irrit. 2, STOT SE 3H351,H315,H319,H336
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : If substance has got into eyes, immediately wash out with water for at least 15 minutes
 Remove contact lenses, if present and easy to do. Continue rinsing.
 Seek immediate medical attention
 Eyewash bottles should be available
Contact with skin : Remove contaminated clothing immediately and drench affected skin with plenty of water. Then wash with soap and water
 Seek medical attention if irritation persists
Inhalation : Fresh air, keep warm and at rest.
 Apply artificial respiration only if patient is not breathing
 Obtain immediate medical attention
Ingestion : If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention
 Rinse mouth with water (do not swallow)
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : May cause respiratory irritation.
 Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
 Symptoms : sore throat, cough, shortness of breath, severe breathing difficulties, headache
Ingestion : After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : Irritating to skin
 Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis
 Symptoms : redness and pain
Eye contact : Irritating to eyes
 Symptoms : redness and pain, impaired vision
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
water, foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
Risk of explosion if heated under confinement
In use, may form flammable/explosive vapour-air mixture
In case of fire, do not breathe fumes. HCl and traces of chlorine may be formed when subjected to heat or combustion.
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
Substance evolves toxic fumes, wear self-contained breathing apparatus
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Ensure adequate ventilation
Wear suitable respiratory protection.
Wear suitable protective clothing including eye/face protection.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Keep away from heat and sources of ignition
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
 
7.2. Conditions for safe storage, including any incompatibilities
 
Keep container tightly closed, in a cool, well ventilated place.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Welding Products
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
dichloromethane; methylene chloride75-09-2TWA100 ppm
STEL200 ppm
National established exposure limits, United Kingdom
dichloromethane; methylene chloride75-09-2TWA100 ppm
STEL300 ppm
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
Keep away from heat and sources of ignition
Personal protection : In all cases handle and use the product in accordance with good industrial hygiene practices.
 Take precautions to avoid contact with skin and eyes when handling the product.
Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with organic gas/vapor cartridge (type AX)
hands and skin : When handling the product wear chemical-resistant gloves (standard EN 374).
 The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through.
 Depending on amount and duration of use and the risk of contact with the product the gloves manufacturer can assist you in the selection of the right glove material and breakthrough time.
Recommended gloves: (polyvinylalcohol)
eyes : Wear face mask giving complete face protection
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
Appearance : physical state : Liquid.
colour : Colourless to yellow.
odour : Characteristic odor.
pH : Not applicable.
Boiling point/range : Not available.
Flash point : None
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 1.292 g/cm3 (@ 20°C).
Solubility in water : Insoluble in water
Auto-ignition : > 200 °C
Viscosity : < 7 mPa.s (@ 40°C).
 
9.2. Other information
 
VOC = volatile organic compounds blank
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No information available
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Avoid overheating
 
10.5. Incompatible materials
 
Strong oxidising agent
Do not mix with bases.
alkaline earth metals
 
10.6. Hazardous decomposition products
 
CO,CO2
traces of chlorine and phosgene
In case of fire, do not breathe fumes. HCl and traces of chlorine may be formed when subjected to heat or combustion.
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
acute toxicity: based on available data the classification criteria are not met
skin corrosion/irritation: Causes skin irritation.
serious eye damage/irritation: Causes serious eye irritation.
respiratory or skin sensitisation: based on available data the classification criteria are not met
germ cell mutagenicity: based on available data the classification criteria are not met
carcinogenicity: Suspected of causing cancer .
toxicity for reproduction: based on available data the classification criteria are not met
STOT-single exposure: May cause drowsiness or dizziness.
STOT repeated exposure: based on available data the classification criteria are not met
aspiration hazard: based on available data the classification criteria are not met
 
Information on likely routes of exposure:
 
Inhalation : May cause irritation.
 Inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
Skin contact : Causes skin irritation.
 Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis
Eye contact : Causes serious eye irritation.
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
dichloromethane; methylene chloride75-09-2LD50 oral rat> 2000 mg/kg
LD50 derm.rat> 2000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Not classified
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
dichloromethane; methylene chloride75-09-2IC50 algae> 662 mg/l
LC50 fish193 mg/l
EC50 daphnia27 mg/l
 
12.2. Persistence and degradability
 
No experimental data available
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Insoluble in water
 
12.5. Results of PBT and vPvB assessment
 
The product does not contain any PBT or vPvB substances.
 
12.6. Endocrine disrupting properties
 
No experimental data available
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Product : This material and its container must be disposed of in a safe way.
Do not discharge into drains or the environment, dispose to an authorised waste collection point.
Contaminated packaging : Disposal should be in accordance with local, state or national legislation
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : 1593
 
14.2. UN proper shipping name
 
Proper shipping name: DICHLOROMETHANE
 
14.3. Transport hazard class(es)
 
Class: 6.1
ADR/RID - Classification code: > 450°C.
 
14.4. Packing group
 
Packing group: III
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: (E)
IMDG - Ems: F-A, S-A
IATA/ICAO - PAX: 655
IATA/ICAO - CAO 663
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Regulation (EC) No 1907/2006 (REACH)
Regulation (EC) No 1272/2008 (CLP)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: H315 : Causes skin irritation.
 H319 : Causes serious eye irritation.
 H336 : May cause drowsiness or dizziness.
 H351 : Suspected of causing cancer .
REVISIONS IN CHAPTRE : Classification according to Regulation (EC) No 1272/2008
 Labelling according to Regulation (EC) No 1272/2008
 8.2. Exposure controls
acronyms and synonyms: TWA = time weight average
 STEL = short time exposure limit
 VOC = volatile organic compounds
 PBT = persistant bioaccumulative toxic
 vPvB = very persitant very bioaccumulative
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.